o-Anisidine_CAS:90-04-0

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CAS number:90-04-0 Weight(g):10kg Price($):Inquiry Time:2017-03-08 11:25:21 Transaction status:Waiting for quotation

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o-Anisidine
CAS No.: 90-04-0
Synonyms:

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  • o-Amnoanisde;
  • 2-Anisidin;
  • 2-methoxy-phenylamine;
  • 2-ANISIDINE;
  • 2-AMINOANISOLE;
  • ORTHO ANISIDINE;
  • 2-methoxybenzenamine;
  • o-Methoxyphenylamine;
  • 2-methoxyaniline;
  • 1-amino-2-methoxy-benzene;
  • O-ANISOLE;
  • O-AMINOANISOLE;
Formula: C7H9NO
Exact Mass: 123.06800
Molecular Weight: 123.15200
PSA: 35.25000
LogP: 1.85860
Reference Price: $3,387/ton
Description
o-Anisidine (2-anisidine) is a yellow liquid with a melting point of -1 to 5 °C and a density of 1.09 g/cm3. The vapor pressure is 0.05 mbar at 20 °C but increases greatly with temperature. It has an aromatic smell and is well absorbed by inhalation, oral ingestion and skin contact. o-Anisidine is a very toxic agent that causes blood, enzyme and nerve damage with cyanosis and the danger of suffocation. The agent is an experimental carcinogen and is strongly suspected to be a human carcinogen also. o-Anisidine has dangerous pollutant properties for water. Non-wastewaters from the production of dyes containing o-Anisidine are listed as RCRA hazardous waste, with the code K181. o-Anisidine is used in the manufacture of dyes. Workers in the dye industry may be occupationally exposed to it. Acute (short-term) exposure to o-anisidine results in skin irritation in humans. Workers exposed to o-anisidine by inhalation for 6 months developed headaches, vertigo, and effects on the blood. Animal studies have reported effects on the blood from chronic (long-term) dermal exposure to o-anisidine. No information is available on the reproductive, developmental, or carcinogenic effects of o-anisidine in humans. Animal studies have reported tumors of the urinary bladder from oral exposure to o-anisidine. EPA has not classified o-anisidine for carcinogenicity. The International Agency for Research on Cancer (IARC) has classified o-anisidine as a Group 2B, possible human carcinogen.

Properties
Appearance & Physical State: yellowish liquid turns brownish on exposure to air
Density: 1.092
Melting Point: 41704ºC
Boiling Point: 225ºC
Flash Point: 107ºC
Refractive Index: 1.573-1.575
Water Solubility: 13 g/L (20 ºC)
Stability: Stable. Incompatible with strong oxidizing agents, acid anhydrides, chloroformates, acids, some plastics, rubber. Air sensitive.
Storage Condition: Refrigerator

Safety Info
RTECS: BZ5410000
Hazard Class: 6.1
Safety Statements: S45-S53
HS Code: 2922199090
Packing Group: III
WGK Germany: 3
RIDADR: UN 2431
Risk Statements: R23/24/25; R45; R68
Hazard Codes: T

GC Analytical MethodTotal: 3 GC Analytical Method

Kovats’ RI, non-polar column, isothermal [Detail]
Column type Active phase Temperature (C) Retention Index (I) Reference
Packed SE-30 180. 1181. Dolecka, Raczynska, et al., 1988
Van Den Dool and Kratz RI, non-polar column, temperature ramp [Detail]
Column type Active phase Temperature (C) Retention Index (I) Reference
Capillary OV-1 1142.7 Gautzsch and Zinn, 1996

 

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